Fundamental Aspects of H2S Adsorption on CPO-27-Ni

作者：Sachin Chavan, Francesca Bonino, Loredana Valenzano, Bartolomeo Civalleri, Carlo Lamberti, Nadia Acerbi, Jasmina H. Cavka, Matthias Leistner, Silvia Bordiga · 发表于：The Journal of Physical Chemistry C · 年份：2013 · DOI：10.1021/jp402440u · 被引用次数：102 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Thermal and Kinetic Analysis、Magnetism in coordination complexes

Adsorption of H2S on the Ni2(dhtp)(H 2O)2·8H2O metal-organic framework (known as CPO-27-Ni or MOF-74-Ni) is characterized by in situ powder X-ray diffraction (PXRD), Fourier transform infrared (FTIR), Raman, and UV-visible spectroscopy) and by first-principles periodic boundary conditions calculations. PXRD results show very high stability of CPO-27-Ni framework in the presence of H 2S. Nevertheless, as evidenced by change in color of the sample from pale yellow to dark green, the adsorption of H2S strongly affects the coordination of Ni sites. FTIR results show the reversible molecular adsorption of H2S. Experimental and computed energies of interaction reveal good agreement. Quantitative data considering energetic aspects (calorimetric measurements) are also included. This work highlights the fundamentals of H 2S adsorption onto the CPO-27-Ni framework.