Enhanced Investigation of CO Methanation over Ni/Al2O3 Catalysts for Synthetic Natural Gas Production

作者：Dacheng Hu, Jiajian Gao, Yuan Ping, Lihua Jia, Poernomo Gunawan, Ziyi Zhong, Guangwen Xu, Fangna Gu, Fabing Su · 发表于：Industrial & Engineering Chemistry Research · 年份：2012 · DOI：10.1021/ie300049f · 被引用次数：291 · 研究领域：Catalysts for Methane Reforming、Catalytic Processes in Materials Science、Catalysis and Oxidation Reactions

CO methanation reaction over the Ni/Al 2 O 3 catalysts for synthetic natural gas production was systematically investigated by tuning a number of parameters, including using different commercial Al 2 O 3 supports and varying NiO and MgO loading, calcination temperature, space velocity, H 2 /CO ratio, reaction pressure, and time, respectively. The catalytic performance was greatly influenced by the above-mentioned parameters. Briefly, a large surface area of the Al 2 O 3 support, a moderate interaction between Ni and the support Al 2 O 3, a proper Ni content (20 wt %), and a relatively low calcination temperature (400 °C) promoted the formation of small NiO particles and reducible β-type NiO species, which led to high catalytic activities and strong resistance to the carbon deposition, while addition of a small amount of MgO (2 wt %) could improve the catalyst stability by reducing the carbon deposition; other optimized conditions that enhanced the catalytic performance included high reaction pressure (3.0 MPa), high H 2 /CO ratio (≥3:1), low space velocity, and addition of quartz sand as the diluting agent in catalyst bed. The best catalyst combination was 20–40 wt % of NiO supported on a commercial Al 2 O 3 (S 4 ) with addition of 2–4 wt % of MgO, calcined at 400–500 °C and run at a reaction pressure of 3.0 MPa. On this catalyst, 100% of CO conversion could be achieved within a wide range of reaction temperature (300–550 °C), and the CH 4 selectivity increased with increasin...