Tunability of Band Gaps in Metal–Organic Frameworks

作者：Chi‐Kai Lin, Dan Zhao, Wen‐Yang Gao, Zhenzhen Yang, Jingyun Ye, Tao Xu, Qingfeng Ge, Shengqian Ma, Di‐Jia Liu · 发表于：Inorganic Chemistry · 年份：2012 · DOI：10.1021/ic301189m · 被引用次数：190 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、X-ray Diffraction in Crystallography、Magnetism in coordination complexes

The tunability of the band gaps in Zn-based metal-organic frameworks (MOFs) has been experimentally demonstrated via two different approaches: changing the cluster size of the secondary building unit (SBU) or alternating the conjugation of the organic linker.