The involvement of the trisulfur radical anion in electron-catalyzed sulfur insertion reactions: facile synthesis of benzothiazine derivatives under transition metal-free conditions
作者:Zheng‐Yang Gu, Jia‐Jia Cao, Shun‐Yi Wang, Shun‐Jun Ji · 发表于:Chemical Science · 年份:2016 · DOI:10.1039/c6sc00240d · 被引用次数:119 · 研究领域:Sulfur-Based Synthesis Techniques、Phenothiazines and Benzothiazines Synthesis and Activities、Synthesis and Catalytic Reactions
S not only provides the sulfur insertion source, but also ignites the reaction through the formation of a trisulfur radical anion and electrons in DMF.