Complexes of 1,2,4-Triazoles, VII [1]. Preparation and Vibrational Spectra of 4,4’-Bi-1,2,4-triazole and Some of its Complexes with Transition Metal(II) Thiocyanates
作者:Jaap G. Haasnoot, Willem L. Groeneveld · 发表于:Zeitschrift für Naturforschung B · 年份:1979 · DOI:10.1515/znb-1979-1105 · 被引用次数:24 · 研究领域:Synthesis and Characterization of Heterocyclic Compounds、Synthesis and biological activity、Click Chemistry and Applications
Abstract The preparation and characterization of 4,4′-bi-1,2,4-triazole is described. The compound is a strong, polydentate, polynucleating nitrogen donor. Two complexes, M(btr)2(NCS)2H2O M=Co, Ni, are described. The vibrational spectra of ligand and complexes are compared. A structure for the complexes is proposed.