(Aminoacetato-κ 2 O , N )bis(quinolin-8-olato-κ 2 O , N )cobalt(III) methanol solvate
作者:Buqin Jing, Shuangming Meng, Jing Han, Bin Wang, Xuemei Li · 发表于:Acta Crystallographica Section E Structure Reports Online · 年份:2008 · DOI:10.1107/s1600536808013135 · 被引用次数:1 · 研究领域:Metal complexes synthesis and properties、Crystal structures of chemical compounds、Metal-Organic Frameworks: Synthesis and Applications
In the crystal structure of the title compound, [Co(C(2)H(4)NO(2))(C(9)H(6)NO)(2)]·CH(3)OH, the Co(III) atom is chelated by two quinolin-8-olate and one glycinate anions in a distorted octa-hedral coordination geometry. The five-membered chelating glycinate ring assumes an envelope conformation. The complex mol-ecules are assembled by inter-molecular N-H⋯O hydrogen bonding.