High-Performance Solution-Processed Non-Fullerene Organic Solar Cells Based on Selenophene-Containing Perylene Bisimide Acceptor

作者：Dong Meng, Dan Sun, Chengmei Zhong, Tao Liu, Bingbing Fan, Lijun Huo, Yan Li, Wei Jiang, Hyosung Choi, Taehyo Kim, Jin Young Kim, Yanming Sun, Zhaohui Wang, Alan J. Heeger · 发表于：Journal of the American Chemical Society · 年份：2015 · DOI：10.1021/jacs.5b11149 · 被引用次数：701 · 研究领域：Organic Electronics and Photovoltaics、Conducting polymers and applications、Perovskite Materials and Applications

Non-fullerene acceptors have recently attracted tremendous interest because of their potential as alternatives to fullerene derivatives in bulk heterojunction organic solar cells. However, the power conversion efficiencies (PCEs) have lagged far behind those of the polymer/fullerene system, mainly because of the low fill factor (FF) and photocurrent. Here we report a novel perylene bisimide (PBI) acceptor, SdiPBI-Se, in which selenium atoms were introduced into the perylene core. With a well-established wide-band-gap polymer (PDBT-T1) as the donor, a high efficiency of 8.4% with an unprecedented high FF of 70.2% is achieved for solution-processed non-fullerene organic solar cells. Efficient photon absorption, high and balanced charge carrier mobility, and ultrafast charge generation processes in PDBT-T1:SdiPBI-Se films account for the high photovoltaic performance. Our results suggest that non-fullerene acceptors have enormous potential to rival or even surpass the performance of their fullerene counterparts.