Facile Synthesis of α‐ and β‐ O ‐Glycosyl Imidates; Preparation of Glycosides and Disaccharides

作者：Richard R. Schmidt, Josef Michel · 发表于：Angewandte Chemie International Edition in English · 年份：1980 · DOI：10.1002/anie.198007311 · 被引用次数：829 · 研究领域：Carbohydrate Chemistry and Synthesis、Enzyme Production and Characterization、Enzyme Catalysis and Immobilization

Simplification of glycoside and saccharide syntheses is possible with the aid of the readily isolable β- and α-glycosyl imidates (1) and (2). These key compounds are conveniently prepared from C-1-unprotected glucopyranose. Compounds of type (2) were formerly unknown.