Selective Hydrodeoxygenation of Lignin‐Derived Phenolic Monomers and Dimers to Cycloalkanes on Pd/C and HZSM‐5 Catalysts

作者：Chen Zhao, Johannes A. Lercher · 发表于：ChemCatChem · 年份：2011 · DOI：10.1002/cctc.201100273 · 被引用次数：329 · 研究领域：Catalysis and Hydrodesulfurization Studies、Catalysis for Biomass Conversion、Lignin and Wood Chemistry

Suffocating phenols: A catalyst system consisting of Pd/C and HZSM-5 shows an extremely high selectivity in removing oxygen-containing groups (hydroxyl, methoxy, ketone, alkylOaryl, and arylOaryl) in lignin-derived substituted phenolic monomers and dimers through a metal-acid catalyzed cascade cleavage of CO bonds in phenolic dimers and the integrated hydrogenation and dehydration reactions in water at 473 K.