Chiral 3D Architectures with Helical Channels Constructed from Polyoxometalate Clusters and Copper–Amino Acid Complexes

作者：Haiyan An, Enbo Wang, Dong‐Rong Xiao, Yangguang Li, Zhong‐Min Su, Lin Xu · 发表于：Angewandte Chemie International Edition · 年份：2005 · DOI：10.1002/anie.200503657 · 被引用次数：579 · 研究领域：Polyoxometalates: Synthesis and Applications、Metal-Organic Frameworks: Synthesis and Applications、Chemical Synthesis and Reactions

A twist to the right, or to the left: Both enantiomers of a new chiral material were synthesized by a rational approach, using enantiopure proline ligands, copper cations, and Keggin polyoxometalate anions as building blocks. The compounds have open-framework structures containing helical channels.