A Water‐Stable Porphyrin‐Based Metal–Organic Framework Active for Visible‐Light Photocatalysis

作者：Alexandra Fateeva, Philip A. Chater, Christopher P. Ireland, Asif Ali Tahir, Yaroslav Z. Khimyak, Paul V. Wiper, James R. Darwent, Matthew J. Rosseinsky · 发表于：Angewandte Chemie International Edition · 年份：2012 · DOI：10.1002/anie.201202471 · 被引用次数：804 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Covalent Organic Framework Applications、Porphyrin and Phthalocyanine Chemistry

Light-harvesting MOFs: A new porous porphyrinic metal-organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible-light photocatalytic activity of this porphyrin-based material is shown for the sacrificial hydrogen evolution from water.