Observation of Cu2+–H2 Interactions in a Fully Desolvated Sodalite‐Type Metal–Organic Framework

作者：Mircea Dincă, Won Seok Han, Yun Liu, Anne Dailly, Craig M. Brown, Jeffrey R. Long · 发表于：Angewandte Chemie International Edition · 年份：2007 · DOI：10.1002/anie.200604362 · 被引用次数：414 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Crystallography and molecular interactions、Boron and Carbon Nanomaterials Research

Metal–H2 binding: A new tetrazolate-based metal–organic framework exhibits high H2 uptake at low temperature and moderate pressure. The evacuation of coordinated solvent molecules from Cu2+ ions within the framework provides strong binding sites for H2 molecules (see picture; Cu purple, C gray, N blue, Cl green).