Enhancement of Photocatalytic and Electrochromic Properties of Electrochemically Fabricated Mesoporous WO3 Thin Films

作者：Sung-Hyeon Baeck, Kyoung‐Shin Choi, Thomas Francisco Jaramillo, Galen Dean Stucky, Eric W. McFarland · 发表于：Advanced Materials · 年份：2003 · DOI：10.1002/adma.200304669 · 被引用次数：477 · 研究领域：Transition Metal Oxide Nanomaterials、Gas Sensing Nanomaterials and Sensors、Advanced Photocatalysis Techniques

Mesoporous WO3 films with a lamellar structure (see Figure) have been synthesized by electrodeposition using sodium dodecyl sulfate (SDS) as a templating agent. Compared to non‐porous WO3 prepared with isopropanol instead of SDS, lamellar phase mesoporous WO3 showed higher photocatalytic activity and greater current density for hydrogen intercalation, probably due to the larger surface area of mesoporous WO3 and more facile charge transport.