Regioselective epoxidations of dienes with manganese(III) porphyrin catalysts

作者：Kenneth Sanders Suslick, Bruce R. Cook · 发表于：Journal of the Chemical Society Chemical Communications · 年份：1987 · DOI：10.1039/c39870000200 · 被引用次数：63 · 研究领域：Porphyrin and Phthalocyanine Chemistry、Metal-Catalyzed Oxygenation Mechanisms、Metalloenzymes and iron-sulfur proteins

A series of sterically hindered manganese porphyrins are shown to be shape-selective catalysts for the epoxidation of a variety of dienes; product ration differences for conjugated vs. non-conjugated dienes indicate the existence of at least two competing epoxidation pathways.