Highly Efficient Dehydrogenation of Formic Acid over a Palladium‐Nanoparticle‐Based Mott–Schottky Photocatalyst

作者：Yiyu Cai, Xin‐Hao Li, Yanan Zhang, Xiao Feng Wei, Kai‐Xue Wang, Jie‐Sheng Chen · 发表于：Angewandte Chemie International Edition · 年份：2013 · DOI：10.1002/anie.201304652 · 被引用次数：249 · 研究领域：Carbon dioxide utilization in catalysis、Advanced Photocatalysis Techniques、Metal-Organic Frameworks: Synthesis and Applications

Exploiting useful contacts: The exceptional catalytic performance of a photocatalyst composed of Pd nanoparticles and mesoporous carbon nitride for the dehydrogenation of formic acid in water at room temperature to produce H2 gas (see picture) is due to enhanced electron enrichment of the Pd nanoparticles through charge transfer at the interface of the Mott–Schottky contact.