Synthesis and Thermal Behavior of a Fused, Tricyclic 1,2,3,4‐Tetrazine Ring System

作者：David E. Chavez, Jeffery C. Bottaro, Mark A. Petrie, Damon A. Parrish · 发表于：Angewandte Chemie International Edition · 年份：2015 · DOI：10.1002/anie.201506744 · 被引用次数：160 · 研究领域：Energetic Materials and Combustion、Chemical Reactions and Mechanisms、Chemical Reaction Mechanisms

This study presents the synthesis and characterization of a fused, tricyclic 1,2,3,4-tetrazine ring system. The molecule is synthesized in a three-step process from 5,5'-dinitro-bis,1,2,4-triazole via a di-N-amino compound. Oxidation to form the azo-coupled fused tricyclic 1,2,3,4-tetrazine is achieved using tert-butyl hypochlorite as the oxidant. The di-N-amino compound and the desired fused tricyclic 1,2,3,4-triazine display interesting thermal behavior and are predicted to be high-performance energetic materials.