Catalytic Synthesis of Magnesium Hydride under Mild Conditions

作者：Borislav Bogdanović, Shih‐Tsien Liao, Manfred Schwickardi, Peter Sikorsky, Bernd Spliethoff · 发表于：Angewandte Chemie International Edition in English · 年份：1980 · DOI：10.1002/anie.198008181 · 被引用次数：94 · 研究领域：Hydrogen Storage and Materials、Ammonia Synthesis and Nitrogen Reduction、Hybrid Renewable Energy Systems

Magnesium hydride, of potential use for reversible storage of hydrogen, has now been synthesized by a method proceeding under mild conditions and which can be performed on a large scale. Especially active catalysts are obtained by reaction of anthracenemagnesium with halides of chromium, titanium, or iron in THF. These solutions are catalytically active at 20°C and under normal pressure.