Synthesis and catalytic properties of MIL-100(Fe), an iron( iii ) carboxylate with large pores

作者：Patricia Horcajada, Suzy Surblé, Christian Serre, Do‐Young Hong, You‐Kyong Seo, Jong‐San Chang, Jean−Marc Grenèche, I. Margiolaki, Gérard Férey · 发表于：Chemical Communications · 年份：2007 · DOI：10.1039/b704325b · 被引用次数：1504 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Chemical Synthesis and Characterization、Covalent Organic Framework Applications

The large-pore iron(III) carboxylate MIL-100(Fe) with a zeotype architecture has been isolated under hydrothermal conditions, its structure solved from synchrotron X-ray powder diffraction data, while Friedel-Crafts benzylation catalytic tests indicate a high activity and selectivity for MIL-100(Fe).