A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal–Organic Frameworks

作者：Vincent Guillerm, Florence Ragon, Meenakshi Dan-Hardi, Thomas Devic, M. Vishnuvarthan, Betiana C. Campo, Alexandré Vimont, Guillaume Clet, Qingyuan Yang, Guillaume Maurin, Gérard Férey, Andrea Vittadini, Silvia Gross, Christian Serre · 发表于：Angewandte Chemie International Edition · 年份：2012 · DOI：10.1002/anie.201204806 · 被引用次数：493 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Magnetism in coordination complexes、Covalent Organic Framework Applications

Brolly good MOFs: A new series of hydrophobic isoreticular porous Zr oxide dicarboxylate MOFs have been prepared (see picture, Zr blue polyhedra, O red, C black). They have a one-dimensional pore system, a rare combination of Lewis acidity and hydrophobic character, and a higher hydrothermal and mechanical stability than their UiO MOF polymorph counterparts.