Photoluminesence and FTIR study of ZnO nanoparticles: the impurity and defect perspective

作者：Gang Xiong, Umapada Pal, Jesús García Serrano, Kamil B. Ucer, Richard T. Williams · 发表于：Physica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics · 年份：2006 · DOI：10.1002/pssc.200672164 · 被引用次数：553 · 研究领域：ZnO doping and properties、Ga2O3 and related materials、Quantum Dots Synthesis And Properties

Abstract We studied the possible correlations between defects and photoluminescence spectra in ZnO nanoparticles of sizes ranging from 43 nm to 73 nm in diameter. The defects and impurity contents were characterized by Fourier‐transform infrared (FTIR) spectroscopy. The results show fewer carboxylate and hydroxyl impurities for particles of larger sizes. No significant variation in oxygen vacancy content was found among samples. Annealing in vacuum at 300 °C significantly reduces the carboxylate and hydroxyl impurities in the samples. The total luminescence intensity (UV + visible) increases as the particle size grows for both the unannealed and annealed samples. This suggests that both types of luminescence are subject to non‐radiative quenching by near surface defect centers, possibly carboxylate and hydroxyl impurities. There may be quenching due to intrinsic lattice defects too. It is found that annealing in vacuum enhances the visible luminescence both absolutely and relative to the UV exciton luminescence. In addition to the 2.5 eV green luminescence peak, a peak centered at 2.8 eV can also be resolved, espeically for the 43 nm sample. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)