An Amine‐Functionalized Titanium Metal–Organic Framework Photocatalyst with Visible‐Light‐Induced Activity for CO 2 Reduction

作者：Yanghe Fu, Dengrong Sun, Yongjuan Chen, Renkun Huang, Zhengxin Ding, Xianzhi Fu, Zhaohui Li · 发表于：Angewandte Chemie International Edition · 年份：2012 · DOI：10.1002/anie.201108357 · 被引用次数：1734 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Advanced Photocatalysis Techniques、Covalent Organic Framework Applications

Let your light shine: the photocatalytic reduction of carbon dioxide to the formate anion under visible light irradiation is for the first time realized over a photoactive Ti-containing metal-organic framework, NH(2)-MIL-125(Ti), which is fabricated by a facile substitution of ligands in the UV-responsive MIL-125(Ti) material.