Isoreticular synthesis and modification of frameworks with the UiO-66 topology

作者：Sergio J. Garibay, Seth M. Cohen · 发表于：Chemical Communications · 年份：2010 · DOI：10.1039/c0cc02990d · 被引用次数：825 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Covalent Organic Framework Applications、Zeolite Catalysis and Synthesis

Amino, bromo, nitro, and naphthalene terephthalic acids were utilized in the isoreticular synthesis of functionalized microcrystalline frameworks with the UiO-66 topology. The amino functionalized framework, UiO-66–NH 2 , was postsynthetically modified with aliphatic and cyclic anhydrides generating amide-functionalized materials.