A Pillared-Layer Coordination Polymer Network Displaying Hysteretic Sorption: [Cu2(pzdc)2(dpyg)]n (pzdc= Pyrazine-2,3-dicarboxylate; dpyg=1,2-Di(4-pyridyl)glycol)

作者：Ryo Kitaura, Kentaro Fujimoto, Shin‐ichiro Noro, Mitsuru Kondo, Susumu Kitagawa · 发表于：Angewandte Chemie International Edition · 年份：2002 · DOI：10.1002/1521-3773(20020104)41:1<133::aid-anie133>3.0.co;2-r · 被引用次数：537 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Covalent Organic Framework Applications、Supramolecular Chemistry and Complexes

A hysteretic adsorption and desorption profile (right) accompanied by a transformation of the crystal structure is observed for the title coordination polymer, which possesses a pillared-layer structure (left), on exposure to H2O or MeOH vapor under pressure.