Ordered Mesoporous Polymers and Homologous Carbon Frameworks: Amphiphilic Surfactant Templating and Direct Transformation

作者：Yu Meng, Dong Gu, Fuqiang Zhang, Yifeng Shi, Haifeng Yang, Zheng Li, Chengzhong Yu, Bo Tu, Dongyuan Zhao · 发表于：Angewandte Chemie International Edition · 年份：2005 · DOI：10.1002/anie.200501561 · 被引用次数：1305 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Mesoporous Materials and Catalysis、Covalent Organic Framework Applications

Ultrahigh stability (>1400 °C) is found for the highly ordered mesoporous polymers and carbon frameworks synthesized from polymerization of phenol and formaldehyde around triblock copolymer templates. Calcination and carbonization lead to removal of the templates and formation of hexagonal and cubic carbon mesostructures with large uniform pores and surface areas (see schematic diagram).