The synthesis of poly(allylamine) containing covalently bound cyclodextrin and its catalytic effect in the hydrolysis of phenyl esters

作者：Toshihiro Seo, Taketoshi Kajihara, Toshiro Iijima · 发表于：Die Makromolekulare Chemie · 年份：1987 · DOI：10.1002/macp.1987.021880906 · 被引用次数：49 · 研究领域：Enzyme function and inhibition、Chemical Reactions and Mechanisms、Chemical Synthesis and Analysis

Abstract A poly(allylamine) {poly[1‐(aminomethyl)ethylene]} (2) containing covalently bound β‐cyclodextrin (CD) residues (3) was synthesized. The inclusion ability of CD was enhanced in this polymer 3. A pronounced catalytic acceleration of the hydrolysis of p‐ and m‐nitrophenyl acetate by 3 as compared with that of 2 indicates the cooperative effect of CD and amino groups on the polymer chains.