Reptation of stars
作者:Pierre Gilles de Gennes · 发表于:Journal de physique · 年份:1975 · DOI:10.1051/jphys:0197500360120119900 · 被引用次数:242 · 研究领域:Rheology and Fluid Dynamics Studies、Mechanical Engineering and Vibrations Research、Mechanics and Biomechanics Studies
We consider the stochastic motions of a star-shaped flexible polymer trapped inside a fixed network. We predict : 1° a renewal time Tr for the star conformations which increases exponentially with the molecular mass M, and 2° a logarithmic relaxation of stress. We do not know whether these properties still hold for a homogeneous melt of stars, or not.