A Rationally Designed Universal Catalyst for Suzuki–Miyaura Coupling Processes

作者：Shawn D. Walker, Timothy E. Barder, Joseph R. Martinelli, Stephen L. Buchwald · 发表于：Angewandte Chemie International Edition · 年份：2004 · DOI：10.1002/anie.200353615 · 被引用次数：867 · 研究领域：Catalytic Cross-Coupling Reactions、Organoboron and organosilicon chemistry、Chemical synthesis and alkaloids

Unprecedented scope, reactivity, and stability are displayed by a new catalyst system. This was demonstrated with general and efficient syntheses of sterically hindered (hetero)biaryls (see examples shown), mild coupling reactions of alkyl boron derivatives, and rapid coupling reactions of aryl chlorides at room temperature.