Ligand‐Directed Strategy for Zeolite‐Type Metal–Organic Frameworks: Zinc( II ) Imidazolates with Unusual Zeolitic Topologies

作者：Xiao‐Chun Huang, Yan‐Yong Lin, Jie‐Peng Zhang, Xiao‐Ming Chen · 发表于：Angewandte Chemie International Edition · 年份：2006 · DOI：10.1002/anie.200503778 · 被引用次数：1817 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Magnetism in coordination complexes、Metal complexes synthesis and properties

Thermally robust porous metal–organic frameworks (MOFs) with zeolitic topologies were constructed by means of a ligand-directed strategy involving molecular tailoring of simple bridging imidazolates with coordinatively unimportant substituents. This led to the isolation of three new MOFs having unusually high symmetries, intriguing topologies such as the supercage shown in the picture, and high thermal stability.