Novel, Acentric Metal–Organic Coordination Polymers from Hydrothermal Reactions Involving In Situ Ligand Synthesis

作者：Ren‐Gen Xiong, Xiang Feng Xue, Hong Lin Zhao, Xiao‐Zeng You, Brendan F. Abrahams, Zi‐Ling Xue · 发表于：Angewandte Chemie International Edition · 年份：2002 · DOI：10.1002/1521-3773(20021018)41:20<3800::aid-anie3800>3.0.co;2-3 · 被引用次数：493 · 研究领域：Synthesis of Tetrazole Derivatives、Metal complexes synthesis and properties、Synthesis and Characterization of Heterocyclic Compounds

The pyridyltetrazolate ligand formed in situ from NaN3 and 3-cyanopyridine in the presence of ZnCl2 or CdCl2 in water affords acentric (1) or chiral (2) coordination polymers, respectively. The corresponding reaction of ZnCl2 with 4-cyanopyridine gives acentric 3 (not shown). Compounds 1–3 are second harmonic generation active.