Lattice Expansion of Highly Oriented 2D Phthalocyanine Covalent Organic Framework Films

作者：Eric L. Spitler, John Colson, Fernando J. Uribe‐Romo, Arthur R. Woll, Marissa Giovino, Abraham Saldivar, William R. Dichtel · 发表于：Angewandte Chemie International Edition · 年份：2012 · DOI：10.1002/anie.201107070 · 被引用次数：289 · 研究领域：Covalent Organic Framework Applications、Luminescence and Fluorescent Materials、Metal-Organic Frameworks: Synthesis and Applications

Expanding into application: covalent organic framework (COF) films are ideally suited for vertical charge transport and serve as precursors of ordered heterojunctions. Their pores, however, were previously too small to accommodate continuous networks of complementary electron acceptors. Four phthalocyanine COFs with increased pore size well into the mesoporous regime are now described.