Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniquesElectronic supplementary information (ESI) available: EXAFS data and Fourier Transform. See http://www.rsc.org/suppdata/cc/b2/b206758g/

作者：Moniek Tromp, Jelle R. A. Sietsma, Jeroen A. van Bokhoven, Gino P. F. van Strijdonck, Richard J. van Haaren, Ad M. J. van der Eerden, Piet W. N. M. van Leeuwen, D.C. Koningsberger · 发表于：Chemical Communications · 年份：2002 · DOI：10.1039/b206758g · 被引用次数：123 · 研究领域：Asymmetric Hydrogenation and Catalysis、Surface Chemistry and Catalysis、Organometallic Complex Synthesis and Catalysis

UV-Vis, combined with ED-XAFS shows, for the first time, the evolution of inactive Pd dimers and trimers, that are a possible first stage in the deactivation process of important palladium catalysed reactions, leading to larger palladium clusters and eventually palladium black.