Self‐Assembly of Interpenetrating Coordination Nets Formed from Interpenetrating Cationic and Anionic Three‐Dimensional Diamondoid Cluster Coordination Polymers

作者：Kai Liang, He‐Gen Zheng, Yinglin Song, Michael F. Läppert, Yi‐Zhi Li, Xinquan Xin, Zi-Xiang Huang, Jiu‐Tong Chen, Shao‐Fang Lu · 发表于：Angewandte Chemie International Edition · 年份：2004 · DOI：10.1002/anie.200460681 · 被引用次数：181 · 研究领域：Magnetism in coordination complexes、Organometallic Compounds Synthesis and Characterization、Metal-Organic Frameworks: Synthesis and Applications

Tetrathiometalates [WS4]2− are the nodal building blocks in a new kind of heterometallic interpenetrating three-dimensional cluster coordination polymer (see picture) that has interesting nonlinear optical properties. The polymer exhibits optical self-focusing behavior and reverse saturable absorption effects.