Giant Pores in a Chromium 2,6‐Naphthalenedicarboxylate Open‐Framework Structure with MIL‐101 Topology

作者：A. Sonnauer, Frank Hoffmann, Michael Fröba, Lorenz Kienle, Viola Düppel, Matthias Thommes, Christian Serre, Gérard Férey, Norbert Stock · 发表于：Angewandte Chemie International Edition · 年份：2009 · DOI：10.1002/anie.200805980 · 被引用次数：215 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、X-ray Diffraction in Crystallography、Covalent Organic Framework Applications

Large, larger, ... Replacement of 1,4-benzenedicarboxylate by 2,6-naphthalenedicarboxylate in the MIL-101 structure leads to an isoreticular mesoporous framework containing cages with diameters of 39 and 46 A. High-throughput methods are employed to determine appropriate reaction conditions. The microcrystalline compound is characterized by molecular simulation techniques, powder X-ray diffraction, N(2)-sorption, and TEM investigations.