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A wellsian ‘three-dimensional’ racemate: eight interpenetrating, enantiomorphic (10,3)-a nets, four right- and four left-handed

作者:Brendan F. Abrahams, Stuart R. Batten, Hasan Hamit, Bernard F. Hoskins, Richard Robson · 发表于:Chemical Communications · 年份:1996 · DOI:10.1039/cc9960001313 · 被引用次数:124 · 研究领域:Synthesis and Characterization of Heterocyclic Compounds、DNA and Nucleic Acid Chemistry、Metal complexes synthesis and properties

The crystal structure of solvated [Zn(tpt)2/3(SiF6)(H2O)2(MeOH)][tpt = 2,4,6-tris(4-pyridyl)-1,3,5-triazine] is comprised of eight independent [Zn3(tpt)2]n networks with the (10,3)-a topology, four of one handedness and four of the other, which interpenetrate in a remarkable way, aspects of which were postulated by A. F. Wells almost twenty years ago.