A mesoporous hydrogen-bonded organic–inorganic framework bearing the isopolymolybdate [Mo 36 O 112 (OH 2 ) 16 ] 8−

作者：R. Atencio, Alexander Briceño, Xacvier Galindo · 发表于：Chemical Communications · 年份：2004 · DOI：10.1039/b413825b · 被引用次数：55 · 研究领域：Polyoxometalates: Synthesis and Applications、Metal-Organic Frameworks: Synthesis and Applications、Chemical Synthesis and Characterization

The mesoporous H-bonded organic-inorganic hybrid material is built up from the assembly of the isopolymolybdate [Mo36O112(OH2)16]8- and H2bipy2+, which displays large interconnected cavities and exhibits a reversible water sorption behaviour while maintaining its striking crystal integrity.