A general synthesis of phosphaalkenes at zirconium with liberation of phosphaformamides

作者：A.J. Roering, L.T. Elrod, Justin K. Pagano, Sarah Lucienne Guillot, Stephanie M. Chan, Joseph M. Tanski, Rory Waterman · 发表于：Dalton Transactions · 年份：2012 · DOI：10.1039/c2dt32322b · 被引用次数：25 · 研究领域：Synthesis and characterization of novel inorganic/organometallic compounds、Organophosphorus compounds synthesis、Coordination Chemistry and Organometallics

A general, atom-economical method for the synthesis of phosphaalkenes is reported via the net coupling of primary alkyl or aryl phosphines with aryl or alkyl isocyanides at zirconium. The phosphorus-containing ligand can be liberated as the phosphaformamide from zirconium by reaction with an organic electrophile.