catena -Poly[disilver(I)( Ag – Ag )-bis(μ 3 -quinoline-3-carboxylato)-1:2:1′κ 3 O : O ′: N ;2:1′′:2′′κ 3 N : O : O ′]

作者：Chun‐Bo Liu, Yao Cong, He-Yi Sun · 发表于：Acta Crystallographica Section E Structure Reports Online · 年份：2012 · DOI：10.1107/s1600536812035209 · 被引用次数：2 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Metal complexes synthesis and properties、Crystal structures of chemical compounds

In the title compound, [Ag(2)(C(10)H(6)NO(2))(2)](n), the Ag(I) atom is coordinated by one N atom and two O atoms from three quinoline-3-carboxyl-ate ligands in a T-shaped fashion, with an additional Ag⋯Ag distance of 2.9468 (6) Å. The ligands connect the Ag(I) atoms into a double-chain structure along [010]. Weak Ag⋯O inter-actions [Ag⋯O = 2.802 (3) and 2.877 (4) Å] link the double-chains into a layer network parallel to (101). π-π inter-actions are also observed in the layer network [centroid-centroid distances = 3.780 (3) and 3.777 (3) Å].