Metal−Metal d−d Interaction through the Discrete Stacking of Mononuclear M(II) Complexes (M = Pt, Pd, and Cu) within an Organic-Pillared Coordination Cage

作者：Michito Yoshizawa, Kosuke Ono, Kazuhisa Kumazawa, Tatsuhisa Kato, Makoto Fujita · 发表于：Journal of the American Chemical Society · 年份：2005 · DOI：10.1021/ja053009f · 被引用次数：119 · 研究领域：Magnetism in coordination complexes、Lanthanide and Transition Metal Complexes、Metal-Organic Frameworks: Synthesis and Applications

Two molecules of planar MII(acac)2 complexes (M = Pt, Pd, and, Cu; acac = acetylacetonato) are efficiently stacked within an organic-pillared coordination cage, exhibiting characteristic spectroscopies (for M = Pt and Pd) and electron spin-spin coupling (for M = Cu) attributable to metal-metal interaction.