Amphiphilic block copolymer nano-fibers via RAFT-mediated polymerization in aqueous dispersed system
作者:Stéphanie Boissé, Jutta Rieger, Khaled Belal, Aurélie Di Cicco, Patricia Beaunier, Min‐Hui Li, Bernadette Charleux · 发表于:Chemical Communications · 年份:2010 · DOI:10.1039/b923667h · 被引用次数:227 · 研究领域:Advanced Polymer Synthesis and Characterization、Block Copolymer Self-Assembly、Covalent Organic Framework Applications
Self-assembled block copolymer nanofibers are attractive materials for multiple applications. We propose here a novel, very simple and straightforward method to prepare polymeric nanofibers at high solids contents directly in water. It is based on an aqueous emulsion polymerization process performed under living radical polymerization conditions, using the RAFT method.