Fluorination of Boronic Acids Mediated by Silver(I) Triflate

作者：Takeru Furuya, Tobias Ritter · 发表于：Organic Letters · 年份：2009 · DOI：10.1021/ol901113t · 被引用次数：304 · 研究领域：Fluorine in Organic Chemistry、Inorganic Fluorides and Related Compounds

A regiospecific Ag-mediated fluorination reaction of aryl- and alkenylboronic acids and esters is reported. The fluorination reaction uses commercially available reagents, does not require the addition of exogenous ligands, and can be performed on a multigram scale. This report discloses the first practical reaction sequence from arylboronic acid to aryl fluorides.