Metal–metalloporphyrin frameworks: a resurging class of functional materials

作者：Wen‐Yang Gao, Matthew Chrzanowski, Shengqian Ma · 发表于：Chemical Society Reviews · 年份：2014 · DOI：10.1039/c4cs00001c · 被引用次数：615 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Porphyrin and Phthalocyanine Chemistry、Covalent Organic Framework Applications

This review presents comprehensively recent progress in metal-metalloporphyrin frameworks (MMPFs) with an emphasis on versatile functionalities. Following a brief introduction of basic concepts and the potential virtues of MMPFs, we give a snapshot of the historical perspective of MMPFs since 1991. We then summarize four effective strategies implemented frequently to construct prototypal MMPFs. MMPFs represent a resurging class of promising functional materials, highlighted with diverse applications including guest-molecule adsorption and separation, catalysis, nano-thin films and light-harvesting.