Three‐Dimensional Interpenetrating Double and Triple Framework Structures in [Cd(bpy)2{Ag(CN)2}2] and [Cd(pyrz){Ag2(CN)3}{Ag(CN)2}]

作者：Takayoshi Soma, Hidetaka Yuge, Toschitake Iwamoto · 发表于：Angewandte Chemie International Edition in English · 年份：1994 · DOI：10.1002/anie.199416651 · 被引用次数：224 · 研究领域：Magnetism in coordination complexes、Synthesis and Characterization of Heterocyclic Compounds、Metal-Organic Frameworks: Synthesis and Applications

No bonding interactions exist between the three interpenetrating framework structures in 1, and all of the two-dimensional networks are constructed by coordinate linkages-these two principles describe the structure of 1 (shown schematically on the right). Compound 1 was prepared from K2[Cd(CN)4], Ag-NO3, and pyrazine at pH 10.