AN EFFICIENT METHOD FOR GLUCOSYLATION OF HYDROXY COMPOUNDS USING GLUCOPYRANOSYL FLUORIDE

作者：Teruaki Mukaiyama, Yoshiyuki Murai, Shin‐ichiro Shoda · 发表于：Chemistry Letters · 年份：1981 · DOI：10.1246/cl.1981.431 · 被引用次数：419 · 研究领域：Carbohydrate Chemistry and Synthesis、Glycosylation and Glycoproteins Research、Synthesis of Organic Compounds

Abstract Glucosides and disaccharides are prepared in good yields from 2,3,4,6-tetra-O-benzyl-β-d-glucopyranosyl fluoride and hydroxy compounds in the presence of stannous chloride and silver perchlorate. In most cases, α-glucosides are predominantly (α⁄β=80⁄20∼92⁄8) obtained.