Mediator oxidation systems in organic electrosynthesis

作者：Yurii N Ogibin, Michaïl N. Elinson, G. I. Nikishin · 发表于：Russian Chemical Reviews · 年份：2009 · DOI：10.1070/rc2009v078n02abeh003886 · 被引用次数：154 · 研究领域：Electrochemical Analysis and Applications、Inorganic and Organometallic Chemistry、Oxidative Organic Chemistry Reactions

The data on the use of mediator oxidation systems activated by electric current (anodic or parallel anodic and cathodic) in organic electrosynthesis are considered and generalised. Electrochemical activation of these systems permits successful application of catalytic versions and easy scaling of mediator-promoted processes. Chemical and environmental advantages of electrochemical processes catalysed by mediator oxidation systems are demonstrated. Examples of the application of organic and inorganic mediators for the oxidation of various classes of organic compounds under conditions of electrolysis are given.