Controlling the Nucleation and Growth of Silver on Palladium Nanocubes by Manipulating the Reaction Kinetics

作者：Jie Zeng, Cun Zhu, Jing Tao, Mingshang Jin, Hui Zhang, Zhiyuan Li, Yimei Zhu, Younan Xia · 发表于：Angewandte Chemie International Edition · 年份：2011 · DOI：10.1002/anie.201107061 · 被引用次数：236 · 研究领域：Gold and Silver Nanoparticles Synthesis and Applications、Nanomaterials for catalytic reactions、nanoparticles nucleation surface interactions

Tell the atoms where to go: By manipulating the rate at which Ag atoms were generated from a precursor, the nucleation and growth of Ag on Pd nanocubes with six equivalent {100} facets were controlled to generate three different types of bimetallic nanocrystals: Pd–Ag hybrid dimers, Pd–Ag eccentric nanobars, and [email protected] core–shell nanocrystals (see scheme).