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Theorem of Corresponding States for Polymers

作者:I. Prigogine, A. Bellemans, C. Naar‐Colin · 发表于:The Journal of Chemical Physics · 年份:1957 · DOI:10.1063/1.1743399 · 被引用次数:64 · 研究领域:Chemistry and Stereochemistry Studies、History and advancements in chemistry

A theorem of corresponding states for polymers (r-mers) is derived for condensed states (liquid and solid). This theorem permits to correlate the thermodynamic properties of an homologous series of r-mer molecules. It gives satisfactory results when applied to the n hydrocarbons series.