Preparation and Characterization of Highly Ordered Graphitic Mesoporous Carbon as a Pt Catalyst Support for Direct Methanol Fuel Cells

作者：Fabing Su, Jianhuang Zeng, Xiaoying Bao, Y.H. Yu, Jim Yang Lee, Xin Zhao · 发表于：Chemistry of Materials · 年份：2005 · DOI：10.1021/cm0502222 · 被引用次数：372 · 研究领域：Mesoporous Materials and Catalysis、Supercapacitor Materials and Fabrication、Catalytic Processes in Materials Science

Mesoporous carbon with graphitic pore walls is highly desired in many electrochemical applications such as fuel cells and lithium ion batteries. In this study, ordered graphitic mesoporous carbon was prepared by chemical vapor deposition (CVD) of benzene in the pores of mesoporous SBA-15 pure-silica template without loading any catalytic species. Nitrogen adsorption, small-angle X-ray scattering, X-ray diffraction, Raman spectrometry, field-emission scanning electron microscopy, transmission electron microscopy, and thermogravimetric analysis techniques were used to characterize the samples. It was observed that the CVD method affords highly ordered mesoporous carbon with graphitic pore walls and low carbon shrinkage because of the high degree of infiltration of pyrolytic carbon. The catalytic performance of the mesoporous carbon as a support for Pt catalyst in room-temperature methanol oxidation was examined. Results show that the specific activity of the Pt catalyst supported on the mesoporous carbon is higher than that of a commercial Pt catalyst form E-TEK.