Recent Advances in Applications of Room‐Temperature Ionic Liquid/Supercritical CO2 Systems

作者：Sergei V. Dzyuba, Richard A. Bartsch · 发表于：Angewandte Chemie International Edition · 年份：2003 · DOI：10.1002/anie.200390070 · 被引用次数：259 · 研究领域：Ionic liquids properties and applications、Analytical Chemistry and Chromatography、Phase Equilibria and Thermodynamics

Duet of Extremes: Efficient and environmentally benign, biphasic systems consisting of ionic liquids and supercritical CO2 (scCO2) have been employed in lipase-catalyzed esterifications (see scheme). The reaction takes place in the ionic liquid with or without a solid support, and the products are removed by means of either batchwise or continuous-flow extraction with supercritical CO2.