1,1′-Azobis(tetrazole): A Highly Energetic Nitrogen-Rich Compound with a N 10 Chain
作者:Thomas Matthias Klapötke, Davin G. Piercey · 发表于:Inorganic Chemistry · 年份:2011 · DOI:10.1021/ic200071q · 被引用次数:259 · 研究领域:Synthesis of Tetrazole Derivatives、Energetic Materials and Combustion
The reaction of 1-aminotetrazole with acidic sodium dichloroisocyanurate allowed isolation of 1,1'-azobis(tetrazole). The rare chain of 10 nitrogen atoms in this compound was confirmed by X-ray crystallography, and the physical and explosive properties of the azo compound were characterized. The title compound possesses both exceedingly high explosive performance and sensitivity.