A Metal−Organic Framework with Entatic Metal Centers Exhibiting High Gas Adsorption Affinity

作者：Shengqian Ma, Hong-Cai “Joe” Zhou · 发表于：Journal of the American Chemical Society · 年份：2006 · DOI：10.1021/ja063538z · 被引用次数：509 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Hydrogen Storage and Materials、Carbon dioxide utilization in catalysis

A metal-organic framework, PCN-9, containing entatic metal centers, has been synthesized and crystallographically characterized. The H2 and CH4 adsorption enthalpies of PCN-9 are among the highest reported thus far.